Diastereoselective formal total synthesis of the DNA polymerase alpha inhibitor, aphidicolin, using palladium-catalyzed cycloalkenylation and intramolecular Diels-Alder reactions.

Toyota M, Sasaki M, Ihara M
Org Lett (2003), Volume 5, Page 1193
PubMed entry Publisher's site

Abstract:

[structure: see text] A novel diastereoselective formal synthesis of ...
[structure: see text] A novel diastereoselective formal synthesis of aphidicolin has been achieved by exploiting a unique characteristic of a bicyclo[3.2.1]octane prepared by employing a palladium-catalyzed cycloalkenylation process.

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